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One of them is called “nuclear spin”, which fundamentally is related to the sensitivity of the nucleus to the effects of external magnetic fields (Figure V. | Free Picture Editor → MoonPic. SHOW OFF - Optimize your solutions and share them with the world using the built-in score histograms, friend leaderboards. Spin crossover (SCO) materials that switch between two different spin states, that is, the high spin (HS) and the low spin (LS) state, with very different optical, magnetic, and structural properties offer a unique platform to understand the consequences induced by the different electronic configurations of transition metal complexes. The analysis of NMR spin–spin coupling leads to a unique insight into the electronic structure of closed-shell molecules, provided one is able to decode the different features of the spin–spin coupling mechanism. First, spin and valley relaxation are suppressed at the valence-band edges as flipping. 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